Physics – Condensed Matter – Materials Science
Scientific paper
2005-02-24
Physics
Condensed Matter
Materials Science
7 pages, 4 figures, submitted to Europhysics Letters on 14th February, 2005
Scientific paper
10.1209/epl/i2005-10081-7
A phase field theory of polycrystalline solidification is presented that is able to describe the nucleation and growth of anisotropic particles with different crystallographic orientation in three dimensions. As opposed with the two-dimensional case, where a single orientation field suffices, in three dimensions, minimum three fields are needed. The free energy of grain boundaries is assumed to be proportional to the angular difference between the adjacent crystals expressed here in terms of the differences of the four symmetric Euler parameters. The equations of motion for these fields are obtained from variational principles. Illustrative calculations are performed for polycrystalline solidification with dendritic, needle and spherulitic growth morphologies.
Bortel Gábor
Granasy László
Pusztai Tamás
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