Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2005-02-08
Physics
Condensed Matter
Soft Condensed Matter
Now 19 pages, no figures, accepted by Journal of Chemical Physics Revision: Add New Section V Spectrum of a Bidisperse System
Scientific paper
10.1063/1.1924602
Quasi-elastic light scattering spectroscopy of dilute solutions of diffusing mesoscopic probe particles is regularly used to examine the dynamics of the fluid through which the probe particles are moving. For probes in a simple liquid, the light scattering spectrum is a simple exponential; the field correlation function $g^{(1)}_{P}(q,\tau)$ of the scattering particles is related to their mean-square displacements $\bar{X^{2}} \equiv < (\Delta x(\tau))^{2}>$ during $\tau$ via $g^{(1)}(q,\tau) = \exp(- {1/2} q^{2} \bar{X^{2}})$. However, historical demonstrations of this expression refer only to ideal Brownian particles in simple liquids, and show that if the form is correct then it is also true that $g^{(1)}(q,\tau) = \exp(- \Gamma \tau)$, a pure exponential in $\tau$. In general, $g^{(1)}_{P}(q,\tau)$ is not a single exponential in time. $g^{(1)}_{P}(q,\tau)$ reflects not only the mean-square particle displacements but also all higher-order mean displacement moments $\bar{X^{2n}}$. A correct general form for $g^{(1)}(q,\tau)$, replacing the generally-incorrect $\exp(- {1/2} q^{2} \bar{X^{2}})$, is obtained. A simple experimental diagnostic determining when the field correlation function gives the mean-square displacements is identified, namely $g^{(1)}(q,\tau)$ reveals $\bar{X^{2}}$ if $g^{(1)}(q,\tau)$ is exponential in $\tau$.
No associations
LandOfFree
Interpretation of Light Scattering Spectra in Terms of Particle Displacements does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Interpretation of Light Scattering Spectra in Terms of Particle Displacements, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Interpretation of Light Scattering Spectra in Terms of Particle Displacements will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-27876