Physics – Condensed Matter – Disordered Systems and Neural Networks
Scientific paper
1997-06-17
J. Phys.: Condens. Matter 10 (1998), L207-L214
Physics
Condensed Matter
Disordered Systems and Neural Networks
RevTex, 6 pages, 2 figures, Revised version
Scientific paper
10.1088/0953-8984/10/14/001
We propose that glass-forming liquids are intrinsically under the influences of both fluctuating interactions and random fields well-known in the field of spin systems. This is due to the frustration between the isotropic and anisotropic parts of effective intermolecular interactions. Our model indicates the existence of two key temperatures relevant to glass transition, the density ordering point T^*_m and the Vogel-Fulcher temperature T_0. Between T^*_m and T_0, a system has features similar to the `Griffiths phase', while below $T_0$ it has those peculiar to the `spin-glass phase'. This picture naturally and universally explains vitrification behavior from its strong to fragile limit.
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