Physics – Condensed Matter – Materials Science
Scientific paper
2003-05-06
Phys. Rev. B 68, 045103 (2003)
Physics
Condensed Matter
Materials Science
9 pages, 9 figures, to appear in Phys. Rev. B
Scientific paper
10.1103/PhysRevB.68.045103
The role that occupied $d$ bands play in the inelastic lifetime of bulk and surface states in Ag is investigated from the knowledge of the quasiparticle self-energy. In the case of bulk electrons, $sp$ bands are taken to be free-electron like. For surface states, the surface band structure of $sp$ states is described with the use of a realistic one-dimensional hamiltonian. The presence of occupied $d$ states is considered in both cases by introducing a polarizable background. We obtain inelastic lifetimes of bulk electrons that are in good agreement with first-principles band-structure calculations. Our surface-state lifetime calculations indicate that the agreement with measured lifetimes of both crystal-induced and image-potential induced surface states on Ag(100) and Ag(111) is considerably improved when the screening of $d$ electrons is taken into account.
Chulkov Evgueni V.
Echenique Pedro M.
Garcia-Lekue Aran
Liebsch Ansgar
Pitarke J. M.
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