Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2009-10-01
Physics
Condensed Matter
Soft Condensed Matter
15 pages, 4 figures, accepted in JPCM special issue
Scientific paper
The quasistationary spreading of a circular liquid drop on a solid substrate typically obeys the so-called Tanner law, with the instantaneous base radius R(t) growing with time as R ~ t^{1/10} -- an effect of the dominant role of capillary forces for a small-sized droplet. However, for droplets of nematic liquid crystals, a faster spreading law sets in at long times, so that R ~ t^alpha with alpha significantly larger than the Tanner exponent 1/10. In the framework of the thin film model (or lubrication approximation), we describe this "acceleration" as a transition to a qualitatively different spreading regime driven by a strong substrate-liquid interaction specific to nematics (antagonistic anchoring at the interfaces). The numerical solution of the thin film equation agrees well with the available experimental data for nematics, even though the non-Newtonian rheology has yet to be taken into account. Thus we complement the theory of spreading with a post-Tanner stage, noting that the spreading process can be expected to cross over from the usual capillarity-dominated stage to a regime where the whole reservoir becomes a diffusive film in the sense of Derjaguin.
Cazabat Anne-Marie
Mechkov Serguei
Oshanin Gleb
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