Structures of Fluorinated Graphenes and Their Signatures

Details Structures of Fluorinated Graphenes and Their Signatures Structures of Fluorinated Graphenes and Their Signatures

2011-03-16

arxiv.org/abs/1103.3291v1

Physics

Condensed Matter

Materials Science

Phys. Rev. B 83, 115432 (2011)

Scientific paper

10.1103/PhysRevB.83.115432

Recent synthesis of fluorinated graphene introduced interesting stable derivatives of graphene. In particular, fluorographene (CF), namely fully fluorinated chair conformation, is found to display crucial features, such as high mechanical strength, charged surfaces, local magnetic moments due to vacancy defects and a wide band gap rapidly reducing with uniform strain. These properties, as well as structural parameters and electronic densities of states are found to scale with fluorine coverage. However, most of the experimental data reported to date neither for CF, nor for other CnF structures complies with the results obtained from first-principles calculations. In this study, we attempt to clarify the sources of disagreements.

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