Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
1999-10-25
Physics
Condensed Matter
Strongly Correlated Electrons
Europhysics Letters, to be published
Scientific paper
10.1209/epl/i1999-00533-6
We show that the asymmetric crystal environment of the V site in the ladder compound NaV$_{2}$O$_{5}$ leads to a strong coupling of vanadium 3d electrons to phonons. This coupling causes fluctuations of the charge on the V ions, and favors a transition to a charge-ordered state at low temperatures. In the low temperature phase the charge fluctuations modulate the spin-spin superexchange interaction, resulting in a strong spin-phonon coupling.
Fischer Manfred
Güntherodt Gernot
Lemmens Peter
Sherman Ya. E.
van Loosdrecht Paul H. M.
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