Bridged-assisted electron transfer. Random matrix theory approach

Details Bridged-assisted electron transfer. Random matrix theory approach Bridged-assisted electron transfer. Random matrix theory approach

1997-09-30

arxiv.org/abs/cond-mat/9709334v1

Physics

Condensed Matter

7 pages, 2 epsf figures included

Scientific paper

10.1016/S0301-0104(98)00138-4

We discuss the effective donor/acceptor coupling for a bridged electron transfer system with a site-diagonal disorder of bridge energies. The average spectral properties of the system are discussed by using the Wegner model (Anderson's type tight-binding Hamiltonian (TBH))for the electronic part of the problem. Spectral properties of the system are discussed using the concept of the functional inverse of the resolvent (``Blue's function'', introduced by Zee) for various limits of noise versus site-site coupling ratio.

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