Soliton-induced optical absorption of halogen-bridged mixed-valence binuclear metal complexes

Details Soliton-induced optical absorption of halogen-bridged mixed-valence binuclear metal complexes Soliton-induced optical absorption of halogen-bridged mixed-valence binuclear metal complexes

2004-07-02

arxiv.org/abs/cond-mat/0407056v1

Physics

Condensed Matter

Strongly Correlated Electrons

to be published in Phys. Rev. B 70, No. 7, August 15 (2004)

Scientific paper

10.1103/PhysRevB.70.115112

Employing the one-dimensional single-band extended Peierls-Hubbard model, we investigate optical conductivity for solitonic excitations in halogen-bridged binuclear metal (MMX) complexes. Photoinduced soliton absorption spectra for MMX chains possibly split into two bands, forming a striking contrast to those for conventional mononuclear metal (MX) analogs, due to the broken electron-hole symmetry combined with relevant Coulomb and/or electron-phonon interactions.

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