Physics – Condensed Matter – Materials Science
Scientific paper
2009-06-28
Physics
Condensed Matter
Materials Science
11 pages, 5figures
Scientific paper
Muon spin relaxation ($\mu$SR) and nuclear magnetic resonance (NMR) experiments revealed that the spin singlet state with an excitation gap of $\sim$200 K is realized from $S = 1/2$ Nb$_4$ tetrahedral clusters in a cluster Mott insulator GaNb$_4$S$_8$. The intercluster cooperative phenomenon to the singlet state at $T_\mathrm{S} = 32$ K is triggered by intracluster Jahn-Teller type structural instability developed from $\sim$$3T_\mathrm{S}$. Referring to the lattice symmetry, the formation of Nb$_8$ octamer (Nb$_4$--Nb$_4$ bond) is suggested.
Kajinami Y.
Nakamura Hiroaki
Tabata Yoshikazu
Takigawa Mitsuaki
Waki Takeshi
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