High-pressure phase transitions - Examples of classical predictability

Physics – Condensed Matter – Statistical Mechanics

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Condensed Matter Physics, Phase Transformations, Pressure Effects, Statistical Mechanics, Thermodynamics, Cosmology, Field Theory (Physics), Hamiltonian Functions, High Pressure

Scientific paper

The applicability of the Savic and Kasanin (1962-1967) classical theory of dense matter to laboratory experiments requiring estimates of high-pressure phase transitions was examined by determining phase transition pressures for a set of 19 chemical substances (including elements, hydrocarbons, metal oxides, and salts) for which experimental data were available. A comparison between experimental and transition points and those predicted by the Savic-Kasanin theory showed that the theory can be used for estimating values of transition pressures. The results also support conclusions obtained in previous astronomical applications of the Savic-Kasanin theory.

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