Free Energy Landscape Of Simple Liquids Near The Glass Transition

Physics – Condensed Matter – Disordered Systems and Neural Networks

Scientific paper

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10 pages, 6 postscript figures, uses iopart.cls and iopart10.clo (included). Invited talk at the ICTP Trieste Conference on "U

Scientific paper

10.1088/0953-8984/12/29/327

Properties of the free energy landscape in phase space of a dense hard sphere system characterized by a discretized free energy functional of the Ramakrishnan-Yussouff form are investigated numerically. A considerable number of glassy local minima of the free energy are located and the distribution of an appropriately defined ``overlap'' between minima is calculated. The process of transition from the basin of attraction of a minimum to that of another one is studied using a new ``microcanonical'' Monte Carlo procedure, leading to a determination of the effective height of free energy barriers that separate different glassy minima. The general appearance of the free energy landscape resembles that of a putting green: deep minima separated by a fairly flat structure. The growth of the effective free-energy barriers with increasing density is consistent with the Vogel-Fulcher law, and this growth is primarily driven by an entropic mechanism.

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