The Transition State in a Noisy Environment

Details The Transition State in a Noisy Environment The Transition State in a Noisy Environment

2005-06-09

arxiv.org/abs/cond-mat/0506231v1

Phys. Rev. Lett. 95 (2005) 058301

Physics

Condensed Matter

Statistical Mechanics

Scientific paper

10.1103/PhysRevLett.95.058301

Transition State Theory overestimates reaction rates in solution because conventional dividing surfaces between reagents and products are crossed many times by the same reactive trajectory. We describe a recipe for constructing a time-dependent dividing surface free of such recrossings in the presence of noise. The no-recrossing limit of Transition State Theory thus becomes generally available for the description of reactions in a fluctuating environment.

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