A new look at radiative association in dense interstellar clouds

Physics – Condensed Matter – Statistical Mechanics

Scientific paper

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Association Reactions, Interstellar Chemistry, Interstellar Matter, Reaction Kinetics, Statistical Mechanics, Ionic Reactions, Molecular Collisions, Molecular Ions, Plasma Clouds

Scientific paper

A corrected statistical theory of radiative association reactions is presented and discussed. Calculations are undertaken to determine the rate coefficients of a variety of radiative association reactions of possible importance in dense interstellar clouds. Our results confirm the suggestion of Smith and Adams that certain radiative association reactions occur quite rapidly at low temperature and are probably important in the synthesis of complex interstellar molecules.

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