The forbidden bands of a'-X system of nitrogen

Physics

Scientific paper

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Scientific paper

Relative vibrational transition probabilities and r-centroids for the a'1[summation operator]-u-X1[summation operator]+g system of nitrogen have been calculated by assuming Morse potentials for the two states. The transition probabilities have been calculated by the method suggested by Fraser and Jarmain (1953) and Jarmain and Fraser (1953). For calculating the r-centroids, the method given by Nicholls (1965) has been employed. Some discussion regarding appearance of the bands of this system and the electronic transition moment has been given.

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