Statistical mechanics of light elements at high pressure. VIII - Thomas-Fermi-Dirac theory for binary mixtures of H with He, C, and O

Physics – Condensed Matter – Statistical Mechanics

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High Pressure, Jupiter (Planet), Light Elements, Planetary Composition, Statistical Mechanics, Thomas-Fermi Model, Atomic Interactions, Binary Mixtures, Carbon, Helium, Hydrogen, Oxygen

Scientific paper

The authors present three-dimensional Thomas-Fermi-Dirac calculations of lattice mixing energies of hydrogen with carbon and oxygen atoms, respectively. The results are used to derive effective interatomic potentials for use in liquid-state mixture calculations. The potentials are then used to derive analytic expressions for binary mixture-free energies and to map out the phase diagrams of mixtures of hydrogen with, respectively, helium, carbon, and oxygen, over a pressure range of ≡5 to ≡103Mbar. Within this pressure range, all three of the latter elements are found to have unlimited solubility in metallic hydrogen over a temperature range which lies above their pure-element melting temperatures, and which includes likely interior temperatures in the Jovian planets.

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