Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2001-01-04
Physics
Condensed Matter
Strongly Correlated Electrons
14 pages, 3 figures included, to be published in Phys. Rev. Lett
Scientific paper
10.1103/PhysRevLett.86.2882
Electron spin resonance data of Cu^{2+} ions in La_{14-x}Ca_{x}Cu_{24}O_{41} crystals (x=9,11,12) reveal a very large width of the resonance line in the paramagnetic state. This signals an unusually strong anisotropy of ~10% of the isotropic Heisenberg superexchange in the Cu-O chains of this compound. The strong anisotropy can be explained by the specific geometry of two symmetrical 90 degree Cu-O-Cu bonds, which boosts the importance of orbital degrees of freedom. Our data show the apparent limitations of the applicability of an isotropic Heisenberg model to the low dimensional cuprates.
Ammerahl Udo
Büchner Bernd
Choi Ki-Young
Freimuth Axel
Grüninger Markus
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