Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2003-05-23
Macromolecules, VOL 37, pp. 621-629 (2004)
Physics
Condensed Matter
Soft Condensed Matter
28 pages; 11 (main) Figs - Revtex4 - Higher resolution Figs can be obtained upon request. To appear in Macromolecules
Scientific paper
10.1021/ma034689e
The adsorption of highly \textit{oppositely} charged flexible polyelectrolytes (PEs) on a charged planar substrate is investigated by means of Monte Carlo (MC) simulations. We study in detail the equilibrium structure of the first few PE layers. The influence of the chain length and of a (extra) non-electrostatic short range attraction between the polycations and the negatively charged substrate is considered. We show that the stability as well as the microstructure of the PE layers are especially sensitive to the strength of this latter interaction. Qualitative agreement is reached with some recent experiments.
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