Physics – Condensed Matter
Scientific paper
Dec 2008
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2008agufmmr53a1732g&link_type=abstract
American Geophysical Union, Fall Meeting 2008, abstract #MR53A-1732
Physics
Condensed Matter
3919 Equations Of State, 3924 High-Pressure Behavior, 3954 X-Ray, Neutron, And Electron Spectroscopy And Diffraction, 3994 Instruments And Techniques, 3999 General Or Miscellaneous
Scientific paper
Experimental high pressure studies are extremely important to planetary science, material science and to the development of condensed matter theory. With experimental difficulties in creating the extreme pressure temperature conditions appropriate to planetary interiors, the approach used is to obtain the thermodynamic data on materials of interest by extrapolating the condensed matter theory which has been benchmarked with the outcome of high pressure experiments to the available high pressures. However the high pressure data used to match the theory heavily depends on the use of pressure media; like ethanol-methanol, silicon oil, argon and helium. Unfortunately still there exist controversy in the literature even with the use of helium as pressure medium as illustrated by the unsettled debate on Zn and Os among different groups. We have measured the equation of state of intermetallic compound AuIn2 and Cd0.8Hg0.2 alloy using ethanol-methanol and argon to the pressure of 20 GPa to confirm the appearance of anomalies in the data due to occurrence of subtle electronic phase transitions. However these anomalies can also be attributed to oriented lattice strains and local non-hydrostatic conditions. We have tried to remove these at room temperature by stabilizing the sample in argon medium in the diamond anvil cell with proper annealing as indicated by the uniformity of the pressure across the sample by ruby fluorescence measurements. We will present the data revealing the electronic transition in AuIn2 at 2.7 GPa and in Cd0.8Hg0.2 near 9 and 18 GPa.
Clark Steve
Godwal B. K.
Jeanloz Raymond
Speziale Simone
Yan James
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