The effect of {11}^B substitution on the superconductivity in MgCNi3

Physics – Condensed Matter – Superconductivity

Scientific paper

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Submitted to Phys. Rev. B

Scientific paper

10.1103/PhysRevB.71.184512

The crystal structure of boron doped superconducting MgC_{1-x}{11}^B_{x}Ni_{3}, studied by powder neutron diffraction, is reported. The solubility limit of boron is determined to be approximately x=0.16. The unit cell expands from a = 3.81089(2) to 3.81966(2) Angstroms as x increases from x=0 to x=0.155. Boron ({11}^B) doping decreases Tc with increasing x: from 7.09K (x=0) to 6.44K (x=0.155).

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