Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2006-08-25
Phys. Rev. E 74, 031608 (2006)
Physics
Condensed Matter
Statistical Mechanics
Scientific paper
10.1103/PhysRevE.74.031608
We study adsorption of liquid at a one-dimensional substrate composed of a single chemical inhomogeneity of width $2L$ placed on an otherwise homogeneous, planar, solid surface. The excess point free energy $\eta (L,T)$ associated with the adsorbed layer's inhomogeneity induced by the substrate's chemical structure is calculated within exact continuum transfer-matrix approach. It is shown that the way $\eta (L,T)$ varies with $L$ depends sensitively on the temperature regime. It exhibits logarithmic divergence as a function of $L$ in the limit $L\to\infty$ for temperatures such that the chemical inhomogeneity is completely wetted by the liquid. In the opposite case $\eta (L,T)$ converges for large $L$ to $2\eta_0$, where $\eta_0$ is the corresponding point tension, and the dominant $L$-dependent correction to $2\eta_0$ decays exponentially. The interaction between the liquid layer inhomogeneities at $-L$ and $L$ for the two temperature regimes is discussed and compared to earlier mean-field theory predictions.
Jakubczyk Pawel
Napiorkowski Marcin
Parry A. O.
No associations
LandOfFree
Point tension in adsorption at a chemically inhomogeneous substrate in two dimensions does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Point tension in adsorption at a chemically inhomogeneous substrate in two dimensions, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Point tension in adsorption at a chemically inhomogeneous substrate in two dimensions will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-111301