Physics – Condensed Matter – Materials Science
Scientific paper
2012-02-20
Chem. Phys. Lett. Vol- 497, Page - 66-69 (2010)
Physics
Condensed Matter
Materials Science
15 pages, 5 figures
Scientific paper
By employing x-ray photoelectron spectroscopy (XPS), we have been able to establish the occurrence of charge-transfer doping in few-layer graphene covered with electron acceptor (TCNE) and donor (TTF) molecules. We have performed quantitative estimates of the extent of charge transfer in these complexes and elucidated the origin of unusual shifts of their Raman G bands and explained the differences in the dependence of conductivity on n- and p-doping. The study unravels the cause of the apparent difference between the charge-transfer doping and electrochemical doping.
Choudhury Debajyoti
Das Balaram
Rao C. N. R.
Sarma Debojit
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