X-ray photoelectron 3s spectra of transition metal oxides

Details X-ray photoelectron 3s spectra of transition metal oxides X-ray photoelectron 3s spectra of transition metal oxides

1999-03-23

arxiv.org/abs/cond-mat/9903354v1

Physics

Condensed Matter

Materials Science

17 pages with 9 embedded postscript figures, uses ioplppt.sty

Scientific paper

We present metal 3s x-ray photoelectron spectra of different transition metal oxides. The values of the 3s exchange splitting for the 3d metal oxides are given as a function of the 3d electron number in the ground state. The spectra were analysed using the simple two-configuration model of the interatomic configuration mixing. The change of the 3s spectra is ascribed to the change of the charge-transfer energy.

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