Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2005-09-06
PhysicaA365:128-131,2006
Physics
Condensed Matter
Statistical Mechanics
Talk given at the Next-SigmaPhi conference in Kolymbari, Crete, Greece, August 13-18, 2005
Scientific paper
10.1016/j.physa.2006.01.036
Two mathematical mechanisms, responsible for the generation of a thermodynamic singularity, are individuated. For a class of short-range, confining potentials, a topology change in some family of configuration space submanifolds is the only possible such mechanism. Two examples of systems in which the phase transition is not accompanied by a such topology change are discussed. The first one is a model with long-range interactions, namely the mean-field phi^4-model, the second example is a one-dimensional system with a non-confining potential energy function. For both these systems, the thermodynamic singularity is generated by a maximization over one variable (or one discrete index) of a smooth function, although the context in which the maximization occurs is very different.
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