Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2012-04-20
Physics
Condensed Matter
Soft Condensed Matter
Submitted to Physical Review Letters
Scientific paper
Particle settling is a pervasive process in nature, and centrifugation is a much versatile separation technique. Yet, the results of settling and ultracentrifugation experiments often appear to contradict the very law on which they are based: Archimedes Principle - arguably, the oldest Physical Law. The purpose of this paper is delving at the very roots of the concept of buoyancy by means of a combined experimental-theoretical study on sedimentation profiles in colloidal mixtures. Our analysis shows that the standard Archimedes' principle is only a limiting approximation, valid for mesoscopic particles settling in a molecular fluid, and we provide a general expression for the actual buoyancy force. This "Generalized Archimedes Principle" accounts for unexpected effects, such as denser particles floating on top of a lighter fluid, which in fact we observe in our experiments.
Buzzaccaro Stefano
Parola Alberto
Piazza Roberto
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