Waveguide Chirped-Pulse Fourier Transform Microwave Cp-Ftmw Spectrum of Allyl Chloride

Details Waveguide Chirped-Pulse Fourier Transform Microwave Cp-Ftmw Spectrum of Allyl Chloride Waveguide Chirped-Pulse Fourier Transform Microwave Cp-Ftmw Spectrum of Allyl Chloride

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..conferh01k&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

Physics

Microwave

Scientific paper

The microwave spectrum of allyl chloride at 0° C was measured from 8.7--18.3 GHz with waveguide chirped-pulse Fourier transform microwave spectroscopy (CP-FTMW). The spectrum consists of contributions from 35Cl and 37Cl isotopomers of the cis and skew isomers. As the vibrational partition function for each of these conformers is approximately 4, the microwave spectrum contains a few thousand transitions with intensities above a 3:1 S/N ratio after a few hours of averaging. We will discuss our progress on the analysis of this spectrum, which has been aided with an automated strategy to find candidate assignments.

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