Viscoelasticity and shear flow of concentrated, non-crystallizing colloidal suspensions: Comparison with Mode-Coupling Theory

Details Viscoelasticity and shear flow of concentrated, non-crystallizing colloidal suspensions: Comparison with Mode-Coupling Theory Viscoelasticity and shear flow of concentrated, non-crystallizing colloidal suspensions: Comparison with Mode-Coupling Theory

2008-10-20

arxiv.org/abs/0810.3551v1

J. Rheol 53, 707 (2009)

Physics

Condensed Matter

Soft Condensed Matter

Scientific paper

10.1122/1.3093088

We present a comprehensive rheological study of a suspension of thermosensitive particles dispersed in water. The volume fraction of these particles can be adjusted by the temperature of the system in a continuous fashion. Due to the finite polydispersity of the particles (standard deviation: 17%), crystallization is suppressed and no fluid-crystal transition intervenes. Hence, the moduli $G'$ and $G"$ in the linear viscoelastic regime as well as the flow curves (shear stress $\sigma(\dot{\gamma})$ as the function of the shear rate $\dot{\gamma}$) could be measured in the fluid region up to the vicinity of the glass transition. Moreover, flow curves could be obtained over a range of shear rates of 8 orders of magnitude while $G'$ and $G"$ could be measured spanning over 9 orders of magnitude. Special emphasis has been laid on precise measurements down to the smallest shear rates/frequencies. It is demonstrated that mode-coupling theory generalized in the integration through transients framework provides a full description of the flow curves as well as the viscoelastic behavior of concentrated suspensions with a single set of well-defined parameters.

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