Vibrational properties of hexagonal LiBC: Infrared and Raman spectroscopy

Physics – Condensed Matter – Superconductivity

Scientific paper

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4 pages, 5 figures (change: Fig 2 replaced)

Scientific paper

10.1103/PhysRevB.68.220510

The paper presents infrared reflectivity and micro-Raman scattering spectra
of LiBC powder pellets. The experiment allowed assignment of frequencies of all
infrared and Raman active zone center modes. Results are compared with
available ab-initio calculations; prediction of large Born effective charges on
the nodes of B-C graphene sheets is confirmed.

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