Vibrational Enhancement of the Effective Donor - Acceptor Coupling

Details Vibrational Enhancement of the Effective Donor - Acceptor Coupling Vibrational Enhancement of the Effective Donor - Acceptor Coupling

2005-05-31

arxiv.org/abs/cond-mat/0505761v1

Physics

Condensed Matter

Mesoscale and Nanoscale Physics

5 pages, 3 figures

Scientific paper

10.1134/1.2137374

The paper deals with a simple three sites model for charge transfer phenomena in an one-dimensional donor (D) - bridge (B) - acceptor (A) system coupled with vibrational dynamics of the B site. It is found that in a certain range of parameters the vibrational coupling leads to an enhancement of the effective donor - acceptor electronic coupling as a result of the formation of the polaron on the B site. This enhancement of the charge transfer efficiency is maximum at the resonance, where the effective energy of the fluctuating B site coincides with the donor (acceptor) energy.

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