Unusual hydrogen atom display in solid acids

Physics – Condensed Matter – Materials Science

Scientific paper

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3 pages, 2 figures. March 30, 2009 - accepted in Acta Cryst. B. May 11, 2009 - declined by C.P. Brock, the Section Editor

Scientific paper

Studying crystal structures of superprotonic phases of alkali metal hydrogen
sulfates and selenates, a very unusual phenomenon has been revealed.
Dynamically disordered hydrogen atoms with low position occupancies are clearly
seen in corresponding electron density maps. To explain this effect, an idea
about a new type of twinning, dynamic twinning, was proposed and discussed.

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