Two-Phase Equilibrium in Small Alloy Particles

Details Two-Phase Equilibrium in Small Alloy Particles Two-Phase Equilibrium in Small Alloy Particles

2004-06-21

arxiv.org/abs/cond-mat/0406477v2

J. Weissm\"uller, P.Bunzel, G. Wilde, Scripta Materialia 51 (2004) 813-818

Physics

Condensed Matter

Materials Science

6 pages, 2 figures

Scientific paper

The coexistence of two phases within a particle requires an interface with a
significant capillary energy. We show that this entails changes in the nature
of alloy phase equilibria at small size. Most notably, the eutectic points in
alloy phase diagrams degenerate into intervals of composition where the alloy
melts discontinuously.

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