Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2008-01-04
Physical Review Letters 100, 106001 (2008)
Physics
Condensed Matter
Statistical Mechanics
5 pages, 3 figures
Scientific paper
10.1103/PhysRevLett.100.106001
Density profiles are the most common measure of inhomogeneous structure in confined fluids, but their connection to transport coefficients is poorly understood. We explore via simulation how tuning particle-wall interactions to flatten or enhance the particle layering of a model confined fluid impacts its self-diffusivity, viscosity, and entropy. Interestingly, interactions that eliminate particle layering significantly reduce confined fluid mobility, whereas those that enhance layering can have the opposite effect. Excess entropy helps to understand and predict these trends.
Errington Jeffrey R.
Goel Gaurav
Krekelberg William P.
Truskett Thomas M.
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