Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2000-06-26
Physics
Condensed Matter
Soft Condensed Matter
Submitted to Phys. Rev. Lett
Scientific paper
We report on a new class of hybrid electronic devices based on a DNA nucleoside (deoxyguanosine lipophilic derivative) whose assembled polymeric ribbons interconnect a submicron metallic gate. The device exhibits large conductivity at room temperature, rectifying behaviour and strong current-voltage hysteresis. The transport mechanism through the molecules is investigated by comparing films with different self-assembling morphology. We found that the main transport mechanism is connected to pi-pi interactions between guanosine molecules in adjacent ribbons, consistently with the results of our first-principles calculations.
Branca E.
Cingolani Roberto
Felice Rosa Di
Garbesi a.
Gottarelli G.
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