Transient photoluminescence enhancement as a probe of the structure of impurity-trapped excitons in CaF$_2$:Yb$^{2+}$

Physics – Condensed Matter – Materials Science

Scientific paper

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Minor corrections. arXiv admin note: text overlap with arXiv:1107.4888v2

Scientific paper

10.1103/PhysRevB.84.113110

We demonstrate a direct measurement of the energy levels of impurity-trapped excitons in CaF$_2$:Yb$^{2+}$. The radically different radiative decay rates of the lowest exciton state and higher excited states enable the generation of a transient photoluminescence enhancement measured via a two-step excitation process. We observe sharp transitions arising from changes of state of localized electrons, broad bands associated with changes of state of delocalized electrons, and broad bands arising from trap liberation.

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