Physics – Condensed Matter – Materials Science
Scientific paper
2012-01-15
Physics
Condensed Matter
Materials Science
Scientific paper
We report on the catalyst-free growth of graphene from amorphous carbon (a-C) by current-induced annealing. This is a novel mechanism that we could witness by in-situ transmission electron microscopy and simulate with molecular dynamics calculations. We observe that small a-C clusters on a graphene substrate rearrange and crystallize into graphene patches due to the high temperatures involved and van-der-Waals interactions with the substrate. Furthermore, we report that in the presence of a-C, graphene can grow from the borders of holes in graphene, healing them out completely. These findings open up new avenues for bottom-up engineering of graphene-based devices.
Avdoshenko Stanislav M.
Barreiro Amelia
Boerrnert Felix
Cuniberti Gianaurelio
Rellinghaus Bernd
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