Thermodynamics of surface tension: application to electrolyte solution

Physics – Condensed Matter – Soft Condensed Matter

Scientific paper

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Special issue of the Journal of Statistical Physics for M.E. Fishers' seventieth birthday

Scientific paper

In this contribution to the special issue of the Journal of Statistical Physics dedicated to Michael Fisher on his 70'th birthday, I shall review two thermodynamically distinct routes for obtaining the interfacial tension of liquid-vapor interfaces in mixtures. A specific application to the calculation of the excess surface tension of aqueous electrolyte solutions will be presented.

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