Thermodynamics of micellization of oppositely charged polymers

Details Thermodynamics of micellization of oppositely charged polymers Thermodynamics of micellization of oppositely charged polymers

2003-04-16

arxiv.org/abs/cond-mat/0304362v1

Physics

Condensed Matter

Soft Condensed Matter

7 pages, 2 figures. Accepted for publication in Europhysics Letters

Scientific paper

10.1209/epl/i2003-00449-1

The complexation of oppositely charged colloidal objects is considered in this paper as a thermodynamic micellization process where each kind of object needs the others to micellize. This requirement gives rise to quantitatively different behaviors than the so-called mixed-micellization where each specie can micellize separately. A simple model of the grand potential for micelles is proposed to corroborate the predictions of this general approach.

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