Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2010-07-02
Phys. Rev. E 83, 041701 (2011)
Physics
Condensed Matter
Soft Condensed Matter
40 pages 19 figures (preprint format). Part of the text and some figures were modified. New figure was included
Scientific paper
We discuss the Lebwohl-Lasher model of nematic liquid crystals in a confined geometry, using Monte Carlo simulation and mean-field theory. A film of material is sandwiched between two planar, parallel plates that couple to the adjacent spins via a surface strength $\epsilon_s$. We consider the cases where the favoured alignments at the two walls are the same (symmetric cell) or different (asymmetric or hybrid cell). In the latter case, we demonstrate the existence of a {\it single} phase transition in the slab for all values of the cell thickness. This transition has been observed before in the regime of narrow cells, where the two structures involved correspond to different arrangements of the nematic director. By studying wider cells, we show that the transition is in fact the usual isotropic-to-nematic (capillary) transition under confinement in the case of antagonistic surface forces. We show results for a wide range of values of film thickness, and discuss the phenomenology using a mean-field model.
Almarza Noe G.
Marguta R. G.
Martinez-Raton Yuri
Velasco Enrique
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