The unified picture for the classical laws of Batschinski and the rectilinear diameter for molecular fluids

Details The unified picture for the classical laws of Batschinski and the rectilinear diameter for molecular fluids The unified picture for the classical laws of Batschinski and the rectilinear diameter for molecular fluids

2011-01-14

arxiv.org/abs/1101.2698v2

Physics

Condensed Matter

Soft Condensed Matter

16 pages, 5 figures

Scientific paper

The explicit relations between the thermodynamic functions of the Lattice Gas model and the fluid within the framework of approach proposed earlier in [V. L. Kulinskii, J. Phys. Chem. B \textbf{114} 2852 (2010)] are derived. It is shown that the Widom line serves as the natural border between the gas-like and the liquid-like states of the fluid. The explanation of the global cubic form of the binodal for the molecular liquids is proposed and the estimate for the amplitude of the binodal opening is obtained.

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