The slope equations: a universal relationship between local structure and glass transition temperature

Details The slope equations: a universal relationship between local structure and glass transition temperature The slope equations: a universal relationship between local structure and glass transition temperature

1998-05-12

arxiv.org/abs/cond-mat/9805138v1

The European Physical Journal B1 (1998) pp. 277-294

Physics

Condensed Matter

Disordered Systems and Neural Networks

31 pages, LaTeX, 16 Postscript figures, mmi@ccr.jussieu.fr

Scientific paper

10.1007/s100510050184

In this article, we present a universal relationship between the glass transition temperature $T_g$ and the local glass structure. The derivation of the simplest expression of this relationship and some comparisons with experimental $T_g$ values have already been reported in a recent letter. We give here the analytical expression of the parameter $\beta$ of the Gibbs-Di Marzio equation and also new experimental probes for the validity of the relationship, especially in low modified binary glasses.

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