Physics
Scientific paper
Jun 2009
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009mss..confeta06c&link_type=abstract
"International Symposium On Molecular Spectroscopy, 64th Meeting, Held 22-26 June, 2009 at Ohio State University. http://molspec
Physics
Microwave
Scientific paper
Tertiary-butyl alcohol is a nearly spherical rotor for which the internal rotation axis of the t-butyl group is close to the c molecular axis in the ac plane. Methyl group torsional spittings are not observed in the ground state. Its 8 to 40 GHz rotational spectrum was reported at this meeting by Valenzuela and Woods in 1974 and in more detail in 1975. The parameters derived at that time from a fit to the E states with J,K≤ 20 have provided the basis for extending the measurements to > 500 GHz. The combined data set extends to J,K > 50 and is fit with the program SPFIT using a common set of parameters for both the A and E states. The general features of the spectrum and the fitting procedure will be described. The resulting molecular constants and their interpretation will be discussed.
E.A. Valenzuela, and R. C. Woods, Abstract MF6, International Symposium on Molecular Spectroscopy, Columbus, OH, 1974
E.A. Valenzuela, and R. C. Woods, Abstract RG15, International Symposium on Molecular Spectroscopy, Columbus, OH, 1975
E.A. Valenzuela, Ph.D. Thesis, University of Wisconsin-Madison, 1975.
H. M. Pickett, J. Mol. Spectrosc. 148 (1991) 271-377.
Caminati Walther
Cohen Adam E.
Drouin Brian J.
Maris Ann
Melandri Sonia
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