The Resonating-Valence-Bond Ground State of Li Nanoclusters

Physics – Condensed Matter – Strongly Correlated Electrons

Scientific paper

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4 pages, 2 figures, 3 tables

Scientific paper

10.1103/PhysRevB.79.035416

We have performed Diffusion Quantum Monte Carlo simulations of Li clusters showing that Resonating-Valence-Bond (RVB) pairing correlations between electrons provide a substantial contribution to the cohesive energy. The RVB effects are identified in terms of electron transfers from s- to p-like character, constituting a possible explanation for the breakdown of the Fermi liquid picture observed in recent high resolution Compton scattering experiments for bulk Li.

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