The microcanonical thermodynamics of finite systems: The microscopic origin of condensation and phase separations; and the conditions for heat flow from lower to higher temperatures

Details The microcanonical thermodynamics of finite systems: The microscopic origin of condensation and phase separations; and the conditions for heat flow from lower to higher temperatures The microcanonical thermodynamics of finite systems: The microscopic origin of condensation and phase separations; and the conditions for heat flow from lower to higher temperatures

2005-03-24

arxiv.org/abs/cond-mat/0503604v1

J.Chem.Phys. 122 (2005) 224111

Physics

Condensed Matter

Statistical Mechanics

23 pages, 2 figures, Accepted for publication in the Journal of Chemical Physics

Scientific paper

10.1063/1.1901658

Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical mechanics especially its key quantity, entropy. Whereas in conventional thermostatistics, the homogeneity and extensivity of the system and the concavity of its entropy are central conditions, these fail for the systems considered here. For example, at phase separation, the entropy, S(E), is necessarily convex to make exp[S(E)-E/T] bimodal in E. Particularly, as inhomogeneities and surface effects cannot be scaled away, one must be careful with the standard arguments of splitting a system into two subsystems, or bringing two systems into thermal contact with energy or particle exchange. Not only the volume part of the entropy must be considered. As will be shown here, when removing constraints in regions of a negative heat capacity, the system may even relax under a flow of heat (energy) against a temperature slope. Thus the Clausius formulation of the second law: ``Heat always flows from hot to cold'', can be violated. Temperature is not a necessary or fundamental control parameter of thermostatistics. However, the second law is still satisfied and the total Boltzmann entropy increases. In the final sections of this paper, the general microscopic mechanism leading to condensation and to the convexity of the microcanonical entropy at phase separation is sketched. Also the microscopic conditions for the existence (or non-existence) of a critical end-point of the phase-separation are discussed. This is explained for the liquid-gas and the solid-liquid transition.

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