The liquid-vapor interface of the restricted primitive model of ionic fluids from a density functional approach

Details The liquid-vapor interface of the restricted primitive model of ionic fluids from a density functional approach The liquid-vapor interface of the restricted primitive model of ionic fluids from a density functional approach

2011-06-16

arxiv.org/abs/1106.3236v1

Condens. Matter Phys., 2011, vol. 14, No. 1, 13603:1-12

Physics

Condensed Matter

Soft Condensed Matter

12 pages, 8 figures

Scientific paper

10.5488/CMP.14.13603

We investigate the liquid-vapor interface of the restricted primitive model for an ionic fluid using a density functional approach. The applied theory includes the electrostatic contribution to the free energy functional arising from the bulk energy equation of state and the mean spherical approximation for a restricted primitive model, as well as the associative contribution, due to the formation of pairs of ions. We compare the density profiles and the values of the surface tension with previous theoretical approaches.

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