The Hydride Anion in an Extended Transition Metal Oxide Array: LaSrCoO_3H_{0.7}

Details The Hydride Anion in an Extended Transition Metal Oxide Array: LaSrCoO_3H_{0.7} The Hydride Anion in an Extended Transition Metal Oxide Array: LaSrCoO_3H_{0.7}

2002-07-27

arxiv.org/abs/cond-mat/0207660v1

Science, vol 295, 1882 (2002)

Physics

Condensed Matter

Strongly Correlated Electrons

6 pages, including 3 figures

Scientific paper

10.1126/science.1068321

We present the synthesis and structural characterisation of a transition metal oxide hydride, LaSrCoO_3H_{0.7}, which adopts an unprecedented structure in which oxide chains are bridged by hydride anions to form a two- dimensional extended network. The metal centers are strongly coupled by their bonding with both oxide and hydride ligands to produce magnetic ordering up to at least 350 K. The synthetic route is sufficiently general to allow the prediction of a new class of transition metal-containing electronic and magnetic materials.

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