The expressions for the 2nd-order mixed partial derivatives of Slater-Koster matrix elements at spherical coordinate singularities

Physics – Condensed Matter – Other Condensed Matter

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9 pages, no figures

Scientific paper

10.1103/PhysRevB.72.165108

In a recent publication it has been shown how to generate derivatives with respect to atom coordinates of Slater-Koster matrix elements for the tight binding (TB) modelling of a system. For the special case of a mixed second partial derivative at coordinate singularities only the results were stated in that publication. In this work, the derivation of these results is given in detail. Though it may seem rather `technical' and only applicable to a very special case, atomic configurations where the connecting vector between the two atoms involved in a two-centre matrix element is aligned along the z-axis (in the usual approach) require results for precisely this case. The expressions derived in this work have been implemented in the DINAMO code.

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