The Electric Double Layer Structure Around Charged Spherical Interfaces

Details The Electric Double Layer Structure Around Charged Spherical Interfaces The Electric Double Layer Structure Around Charged Spherical Interfaces

2011-10-24

arxiv.org/abs/1110.5309v2

J. Chem. Phys. 136, 044106 (2012)

Physics

Condensed Matter

Soft Condensed Matter

7 pages, 5 figures

Scientific paper

10.1063/1.3681147

We derive a formally simple approximate analytical solution to the
Poisson-Boltzmann equation for the spherical system via a geometric mapping.
Its regime of applicability in the parameter space of the spherical radius and
the surface potential is determined, and its superiority over the linearized
solution is demonstrated.

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