Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2011-04-10
Phys. Rev. Lett. 106, 186103 (2011)
Physics
Condensed Matter
Soft Condensed Matter
4 pages, 3 figures
Scientific paper
Young's classic analysis of the equilibrium of a three-phase contact line ignores the out-of-plane component of the liquid-vapor surface tension. While it has long been appreciated that this unresolved force must be balanced by elastic deformation of the solid substrate, a definitive analysis has remained elusive because conventional idealizations of the substrate imply a divergence of stress at the contact line. While a number of theories of have been presented to cut off the divergence, none of them have provided reasonable agreement with experimental data. We measure surface and bulk deformation of a thin elastic film near a three-phase contact line using fluorescence confocal microscopy. The out-of-plane deformation is well fit by a linear elastic theory incorporating an out-of-plane restoring force due to the surface tension of the gel. This theory predicts that the deformation profile near the contact line is scale-free and independent of the substrate elastic modulus.
Dufresne Eric R.
Jerison Elizabeth R.
Wilen Larry A.
Xu Ye
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