The application of the global isomorphism to the study of liquid-vapor equilibrium in two and three dimensional Lenard-Jones fluids

Physics – Condensed Matter – Statistical Mechanics

Scientific paper

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9 pages, 2 figures

Scientific paper

10.1063/1.3499857

We analyze the interrelation between the coexistence curve of the Lennard-Jones fluid and the Ising model in two and three dimensions within the global isomorphism approach proposed earlier [V. L. Kulinskii, J. Phys. Chem. B \textbf{114} 2852 (2010)]. In case of two dimensions we use the exact Onsager result to construct the binodal of the corresponding Lennard-Jones fluid and compare it with the results of the simulations. In the three dimensional case we use available numerical results for the Ising model for the corresponding mapping. The possibility to observe the singularity of the binodal diameter is discussed.

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