Temperature dependence of electric resistance and magnetoresistance of pressed nanocomposites of multilayer nanotubes with the structure of nested cones

Physics – Condensed Matter – Materials Science

Scientific paper

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8 pages, 4 figures. EM photographic images on figures 1a, 1b, 1c attached as JPG files. For correspondence mail to tsebro@sci.

Scientific paper

10.1134/1.558593

Bulk samples of carbon multilayer nanotubes with the structure of nested cones (fishbone structure) suitable for transport measurements, were prepared by compressing under high pressure (~25 kbar) a nanotube precursor synthesized through thermal decomposition of polyethylene catalyzed by nickel. The structure of the initial nanotube material was studied using high-resolution transmission electron microscopy. In the low-temperature range (4.2 - 100 K) the electric resistance of the samples changes according to the law ln \rho ~ (T_0/T)^{1/3}, where T_0 ~ 7 K. The measured magnetoresistance is quadratic in the magnetic field and linear in the reciprocal temperature. The measurements have been interpreted in terms of two-dimensional variable-range hopping conductivity. It is suggested that the space between the inside and outside walls of nanotubes acts as a two-dimensional conducting medium. Estimates suggest a high value of the density of electron states at the Fermi level of about 5 10^{21} eV^{-1} cm^{-3}.

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